Magnetic and transport behavior of Fe 2O 3/polypyrrole nanocomposites

Z. Guo, K. Shin, A. B. Karki, D. P. Young, R. B. Kaner, H. T. Hahn

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

The effect of iron oxide nanoparticles on the physicochemical properties of polypyrrole (PPy) was investigated. Discrete nanoparticles were observed as compared with the network structure of the PPy synthesized without iron oxide nanoparticles. The electrical conductivity of the nanocomposites was observed to increase dramatically after the initial addition of nanoparticles due to the crystallinity and more condensed structure of the PPy. However, the higher nanoparticle loading was observed to decrease the conductivity due to the dominating insulating iron oxide nanoparticles. Standard four-probe measurements indicated a three-dimensional variable-range-hopping conductivity mechanism. The magnetic properties of the fabricated nanocomposites were dependent on the particle loading. Ultrasonic stirring was observed to have a favorable effect on the protection of iron oxide nanoparticles from dissolution in the acidic reactant. A tight polymer structure surrounds the magnetic nanoparticles, as compared to a complete loss of the magnetic nanoparticles during conventional mechanical stirring for the microparticle filled PPy composite fabrication.

Original languageEnglish
Title of host publicationAmerican Society for Composites - 22nd Technical Conference of the American Society for Composites 2007 - Composites
Subtitle of host publicationEnabling a New Era in Civil Aviation
Pages1624-1638
Number of pages15
StatePublished - 2007
Event22nd Technical Conference of the American Society for Composites 2007 - Composites: Enabling a New Era in Civil Aviation - Seattle, WA, United States
Duration: 17 Sep 200719 Sep 2007

Publication series

NameAmerican Society for Composites - 22nd Technical Conference of the American Society for Composites 2007 - Composites: Enabling a New Era in Civil Aviation
Volume3

Conference

Conference22nd Technical Conference of the American Society for Composites 2007 - Composites: Enabling a New Era in Civil Aviation
Country/TerritoryUnited States
CitySeattle, WA
Period17/09/0719/09/07

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