Facile electrodeposition of V-doped CoP on vertical graphene for efficient alkaline water electrolysis

Linh Truong, Sanjib Baran Roy, Sahng Kyoon Jerng, Jae Ho Jeon, Sunghun Lee, Seung Hyun Chun

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12 Scopus citations

Abstract

In this work, we demonstrate a highly enhanced electrocatalytic activity of vanadium-doped CoP (V-CoP), directly grafted on a vertical graphene/carbon cloth electrode (VG/CC) by a facile electrochemical deposition method. Impressively, V-CoP/VG/CC exhibited a superior catalytic activity toward the hydrogen evolution reaction (HER) in alkaline solution. Compared to CoP/VG/CC, V-doping decreased the overpotential for HER at 10 mA cm-2 by more than half to 40 mV. The new catalyst even outperformed Pt/C beyond 150 mA cm-2. The overpotential for OER at 50 mA cm-2 was merely 314 mV, more than 100 mV lower than that of IrO2. Moreover, our novel catalyst worked as an excellent bifunctional catalyst with a low cell voltage of 1.69 V to achieve a current density of 50 mA cm-2. Detailed characterizations revealed that the V-doping in CoP resulted in improved electrical conductivity and increased active sites. Our findings highlight the significant advantage of V doping on the catalytic activities of CoP, already boosted by VG. Furthermore, concurrent doping with the electrodeposition of catalyst offers a new approach for practical water electrolysis.

Original languageEnglish
Pages (from-to)13016-13020
Number of pages5
JournalRSC Advances
Volume10
Issue number22
DOIs
StatePublished - 14 Apr 2020

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© 2020 The Royal Society of Chemistry.

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